1990 – 1999

53. Organomanganese (II) reagents XXI: Réaction d’un composé organomanganeux avec une énone conjuguée; influence d’un acide de Lewis, d’un sel de fer ou d’un sel de nickel
G. Cahiez, M. Alami
J. Organomet. Chem. 1990, 397, 291.

54. A simple high yield procedure for the copper-catalyzed conjugate addition of organo-magnesium reagents to a,b-ethylenic esters
G. Cahiez, M. Alami
Tetrahedron Lett. 1990, 31, 7425.

55. Organomanganese reagents XXII. Copper-Catalyzed Conjugate Addition of Organomanganese Reagents to a,b-Ethylenic Esters
G. Cahiez, M. Alami
Tetrahedron Lett. 1990, 31, 7423.


56. Organomanganese reagents XXIII. Manganese-Catalyzed Acylation of Organomagnesium Compounds by Carboxylic Acid Chlorides
G. Cahiez, B. Laboue
Tetrahedron Lett. 1992, 33, 4439.

57. A New Simple Route to Furanic Ketone; Preparation of Elsholtzione, Naginata Ketone and Perilla Ketone
G. Cahiez, P.-Y. Chavant, E. Metais
Tetrahedron Lett. 1992, 33, 5245.

58. Addition of Polyfunctional and Pure (E or Z) Alkenylcopper and Arylcopper Compounds to Alkylidenemalonates
G. Cahiez, P. Venegas, C. E. Tucker, T. N. Majid, P. Knochel
J. Chem. Soc., Chem. Commun. 1992, 1406.

59. Los Compuestos Organomanganosos
G. Cahiez, P. Venegas
Politecnica 1992, 17, 97.


60. Copper-Catalyzed Alkylation of Organomanganese Chloride Reagents
G. Cahiez, S. Marquais
Synlett 1993, 45.

61. Manganese-Copper-Catalyzed Conjugate Addition of Organomagnesium Reagents to a, b Ethylenic Ketones: Preparation of 2-(1,1-Dimethylpentyl) 5-Methyl Cyclohexanone from Pulegone
G. Cahiez, S. Marquais, M. Alami
Organic Syntheses 1993, 72, 135.


62. Preparation of Alkylzinc bromides Using a New Mn/Cu Catalyzed Bromine-Zinc Exchange Reaction
Klement, P. Knochel, K. Chau, G. Cahiez
Tetrahedron Lett. 1994, 35, 1177.

63. Highly Regioselective Monoalkylation of Ketones via Manganese Enolates Prepared from Manganese Amides
G. Cahiez, B. Figadère, P. Cléry
Tetrahedron Lett. 1994, 35, 3065.

64. Highly Regioselective Monoalkylation of Ketones via Manganese Enolates Prepared from Lithium Enolates
G. Cahiez, K. Chau, P. Cléry
Tetrahedron Lett. 1994, 35, 3069.

65. Highly Regio and Stereoselective Preparation of (Z) Silyl Enol Ethers from Ketones via Manganese Enolates
G. Cahiez, B. Figadère, P. Cléry
Tetrahedron Lett. 1994, 35, 6295.

66. Stereospecific Synthesis of Polyfunctional Alkenes by the Cross-Coupling of Functionalized Zinc-Copper Reagents with Alkenyl Iodides
S. Marquais, G. Cahiez, P. Knochel
Synlett 1994, 849.


67. Deprotonation of Ketones to Mn-Enolates by Phenylmanganese Chloride in the Presence of a Catalytic Amount of Amine
G. Cahiez, M. Kanaan, P. Cléry
Synlett 1995, 191.

68. Enantioselective Preparation of a-Acyloxy Ketones from α-Hydroxy and a-Amino Acids.
G. Cahiez, E. Métais
Tetrahedron Lett. 1995, 36, 6449.

69. Manganese Dioxide
G. Cahiez, M. Alami
Encyclopedia of Reagents for Organic Synthesis, Ed. L. Paquette, Wiley, Chichester (England), 1995, 3229.

70. Manganese (II) Chloride
G. Cahiez
Encyclopedia of Reagents for Organic Synthesis, Ed. L. Paquette, Wiley, Chichester (England), 1995, 3227.

71. Butyl Manganese Chloride and Related Reagents
G. Cahiez
Encyclopedia of Reagents for Organic Synthesis, Ed. L. Paquette, Wiley, Chichester (England), 1995, 925.

72. Benzoyl Chloride
G. Cahiez
Encyclopedia of Reagents for Organic Synthesis, Ed. L. Paquette, Wiley, Chichester (England), 1995, 309.

73. Aplicaciones sintéticas de los compuestos organomanganosos RMnX y compuestos analogos
G. Cahiez
Anales de Quimica 1995, 91, 561.


74. Cu-Catalyzed Alkylation and Fe-Catalyzed Alkenylation of Organomanganese Reagents
G. Cahiez, S. Marquais
Pure and Appl. Chem. 1996, 68, 53.

75. Highly Chemo- and Stereoselective Fe-Catalyzed Alkenylation of Organomanganese Reagents
G. Cahiez, S. Marquais
Tetrahedron Lett. 1996, 37, 1773.

76. Preparation of Polyfunctional Aryl and Alkenyl Zinc Halides from Functionalized Unsaturated Organolithiums and their Reactivity in Cross-Coupling and Conjugated Addition Reactions
Klement, M. Rottländer, C.E. Tucker, T. N. Majid, P. Knochel, P. Venegas, G. Cahiez
Tetrahedron, 1996, 52, 7201.

77. Novel organomanganese(II) complexes active as homogeneous catalysts in manganese(II)/ copper(I) catalyzed carbon-carbon bond formation reactions
G. Donkervoort, J. L. Vicario, J. T. B. H. Jastrzebski, G. Cahiez, G. Van Koten
Recueil de travaux chimiques des Pays-Bas 1996, 115, 547.

78. New Mixed Metal (Mn/Cu) Catalyzed Stereoselective Cyclisations.
E. Riguet, I. Klement, C. K. Reddy, G. Cahiez, P. Knochel
Tetrahedron Lett. 1996, 37, 5865.


79. Preparation and Reactivity of Functionalized Aryl and Alkenylmanganese Halides
Klement, H. Stadtmüller, P. Knochel, G. Cahiez
Tetrahedron Lett. 1997, 38, 1927.

80. Enantioselective Synthesis of d-Ketobutanolides from (L)‑Glutamic Acid via Organomanganese Reagents
G. Cahiez, E. Métais
Tetrahedron Asymmetry 1997, 8, 1373.

81. An Efficient Synthesis of Stereodefined Enynes and Dienes via Pd-Catalyzed Reaction of Chloroenynes and Chlorodienes with Grignard Reagents
P. Ramiandrasoa, B. Bréhon, A. Thivet, M. Alami, G. Cahiez
Tetrahedron Lett. 1997, 38, 2447.

82. Palladium-Catalyzed Selective Synthesis of Unsymmetrical Biaryls from Aryl Halides or Triflates and Organomanganese Reagents
E. Riguet, M. Alami, G. Cahiez
Tetrahedron Lett. 1997, 38, 4397.

83. Preparation of 2-Zincio-1,3-Dithianes and di(1,3-dithian-2-yl)zinc and their reaction with highly functionalyzed halides and a,b-unsaturated carbonyl compounds
Ceré, S. DeAngelis, S. Pollicino, A. Ricci, C.K. Reddy, P. Knochel, G. Cahiez
Synthesis 1997, 1174.


84. Stereoselective Nickel and Manganese Catalyzed Cyclisations of 5-Haloketones
Stüdemann, M. Ibrahim-Ouali, G. Cahiez, P. Knochel
Synlett 1998, 143.

85. Salt Effects on the Reactivity and the Stability of Organomanganese Reagents
G. Cahiez, L. Razafintsalama, B. Laboue, F. Chau.
Tetrahedron Lett. 1998, 39, 849.

86. Stereoselective Manganese-Catalyzed Coupling Reaction of Conjugated Chloroenynes and Chlorodienes with Grignard Reagents
M. Alami, P. Ramiandrasoa, G. Cahiez
Synlett 1998, 325.

87. Highly Stereo- and Chemoselective Iron-Catalyzed Alkenylation of Organomagnesium Compounds
G. Cahiez, H. Avedissian
Synthesis 1998, 1199.

88. Preparation of Highly Functionalized Grignard Reagents Via an Iodine-Magnesium Exchange Reaction. Application to Solid Phase Synthesis
L. Boymond, M. Rottländer, G. Cahiez, P. Knochel
Angew. Chem. Int. Ed. 1998, 37, 1701.

89. Cobalt-Catalyzed Alkenylation of Organomagnesium Reagents
G. Cahiez, H. Avedissian
Tetrahedron Lett. 1998, 39, 6159.

90. Cobalt-Catalyzed Alkenylation of Zinc Organometallics
H. Avedissian, L. Bérillon, G. Cahiez, P. Knochel
Tetrahedron Lett. 1998, 39, 6163.

91. Novel tridentate diamino organomanganese(II) complexes as homogeneous catalysts in manganese(II)/copper(II) catalyzed carbon-carbon bond forming reactions
G. Donketvoort, J.L. Vicario, J.T.B.H. Jastrzebski, R.A. Gossage, G. Cahiez, G. Van Koten
J. Organomet. Chem. 1998, 558, 61.

92. Preparation of Highly Functionalized Pyridylmagnesium Reagents for the Synthesis of Polyfunction Pyridines
G. Berillon, A. Leprêtre, A. Turck, N. Plé, G. Quéguiner, G. Cahiez, P. Knochel
Synlett 1998, 1359.

93. Regioselective Monoalkylation of Manganese Enolates: Preparation of 2-Benzyl-6-Methylcyclohexanone from 2-Methylcyclohexanone
G. Cahiez, F. Chau, B. Blanchot
Org. Synth. 1998, 76, 239.


94. Stereoselective Preparation of Functionalized Alkenylmagnesium Reagents via an Iodine-Magnesium Exchange Reaction
Rottländer, L. Boymond, G. Cahiez, P. Knochel
J. Org. Chem. 1999, 64, 1080.

95. A New Convenient Procedure to Prepare Organomanganese Reagents from Organic Halides and Activated Manganese
G. Cahiez, A. Martin, T. Delacroix
Tetrahedron Lett. 1999, 40, 6407.

96. Manganese-catalyzed substitution of activated arylhalides (X= Cl, Br, I and F) and aryl methyl ether by organomagnesium reagents
G. Cahiez, F. Lepifre, P. Ramiandrasoa
Synthesis 1999, 2138.

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Selective Organic Synthesis and Organometallic Catalysis